Monofunctionalized Fluorinated Bambusurils and Their Conjugates for Anion Transport and Extraction
| Authors | |
|---|---|
| Year of publication | 2022 |
| Type | Article in Periodical |
| Magazine / Source | Journal of Organic Chemistry |
| MU Faculty or unit | |
| Citation | |
| web | https://doi.org/10.1021/acs.joc.2c00870 |
| Doi | http://dx.doi.org/10.1021/acs.joc.2c00870 |
| Keywords | Anions; Assays; Extraction; Macrocycles; Reaction products |
| Description | Bambusurils are macrocyclic molecules that are known for their high binding affinity and selectivity toward anions. Here, we present the preparation of two bambusurils bearing fluorinated substituents and one carboxylic function. These monofunctionalized bambusurils were conjugated with crown ether and cholesterol units. The resulting conjugates were successfully tested in liquid–liquid extraction of inorganic salts and chloride/bicarbonate transport across lipid bilayers. |
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