Příprava 3,3,4,4-tetramethylsukcinimidoderivátů fenylchlorfosfanů a fenylchlorfosforanů
| Title in English | Synthesis of 3,3,4,4-tetramethylsuccinimidate derivates of chlorophenylphosphines and chlorophenylphosphoranes |
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| Authors | |
| Year of publication | 2005 |
| Type | Article in Proceedings |
| Conference | ChemZi, 57. sjezd chemických společností |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | tetramethylsuccinimide; phosphines; phosphoranes; substitution |
| Description | We prepared and isolated new compounds phenyl_bis(3,3,4,4_tetramethylsuccinimido)phosphine (PhPT2), diphenyl_3,3,4,4_tetramethylsuccinimidophosphine (Ph2PT), phenyl-bis(3,3,4,4_tetramethylsuccinimido)phosphinoxide (PHPOT2) and triphenylphosphinoxide _ 3,3,4,4_tetramethylsuccinimide (Ph3PO.TH). By the reactions of chlorophenylphosphoranes with TH or KT compounds with phosphoryl group was always formed, that is why the substitution of all atoms of chlorine was not observed. |
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