Příprava 3,3,4,4-tetramethylsukcinimidoderivátů fenylchlorfosfanů a fenylchlorfosforanů

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Title in English Synthesis of 3,3,4,4-tetramethylsuccinimidate derivates of chlorophenylphosphines and chlorophenylphosphoranes
Authors

VYŠVAŘIL Martin DASTYCH Dalibor

Year of publication 2005
Type Article in Proceedings
Conference ChemZi, 57. sjezd chemických společností
MU Faculty or unit

Faculty of Science

Citation
Field Inorganic chemistry
Keywords tetramethylsuccinimide; phosphines; phosphoranes; substitution
Description We prepared and isolated new compounds phenyl_bis(3,3,4,4_tetramethylsuccinimido)phosphine (PhPT2), diphenyl_3,3,4,4_tetramethylsuccinimidophosphine (Ph2PT), phenyl-bis(3,3,4,4_tetramethylsuccinimido)phosphinoxide (PHPOT2) and triphenylphosphinoxide _ 3,3,4,4_tetramethylsuccinimide (Ph3PO.TH). By the reactions of chlorophenylphosphoranes with TH or KT compounds with phosphoryl group was always formed, that is why the substitution of all atoms of chlorine was not observed.
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