Determination of cadmium by ETAAS after electrodeposition on a Pd-coated graphite probe
| Title in English | Determination of cadmium by electrothermal atomic absorption spectrometry after electrodeposition on Pd-coated graphite probe |
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| Authors | |
| Year of publication | 2004 |
| Type | Article in Proceedings |
| Conference | 6th European Furnace Symposium and 11th Solid Sampling Colloquium with Atomic Spectrometry. Book of Abstracts. |
| MU Faculty or unit | |
| Citation | |
| Field | Analytic chemistry |
| Keywords | atomic absorption spectrometry; electrothermal atomization; electrodeposition; cadmium |
| Description | Determination of cadmium in real samples with complicated matrix by electrothermal atomic absorption spectrometry (ETAAS) is influenced by chemical and spectral interferences. The interferences can be suppressed by applying various procedures. A special technique of separation is the electrochemical preconcentration of the analyte on electrodes. Commercial electrographite ridge probe coated electrochemically with palladium was used as a working electrode and was inserted with the electrodeposited analyte into the atomizer. Potentiostatic electrodeposition of cadmium on the graphite probe electrochemically coated with palladium was applied to the determination of cadmium in sea water and urine. |
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