ETAAS determination of cadmium with preconcentration using an electrochemical microcell

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Authors

KNÁPEK Jan KOMÁREK Josef KRÁSENSKÝ Pavel

Year of publication 2004
Type Article in Proceedings
Conference 6th European Furnace Symposium and 11th Solid Sampling Colloquium with Atomic Spectrometry. Book of Abstracts.
MU Faculty or unit

Faculty of Science

Citation
Field Analytic chemistry
Keywords atomic absorption spectrometry; electrothermal atomization; electrochemical deposition; cadmium
Description For the elimination of interferences at determination of cadmium by atomic absorption spectrometry with electrothermal atomization (ETAAS) various separation techniques are frequently used. As a special technique for separation of analyte from the sample can be mentioned electrochemical deposition of analyte on electrodes. Conditions of electrodeposition of cadmium on the graphite working electrode were studied, as well as modifications of this electrode and forms of transport of dissolved deposit into graphite atomizer. Electrodeposition with injection of dissolved deposit into electrothermal atomizer was applied to the determination of cadmium in sea water and urine.
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