The Intramolecular Cycloadditon Reaction of  N'-Alkyl-N3-[[(2-cyanophenyl)imino](phenyl)methyl]thioureas

Hassan,  Walid Fathalla M.; Čajan,  Michal; Marek,  Jaromír; Pazdera,  Pavel

The Intramolecular Cycloadditon Reaction of N'-Alkyl-N3-[[(2-cyanophenyl)imino](phenyl)methyl]thioureas

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Authors	MOHAMED Walid Fathalla ČAJAN Michal MAREK Jaromír PAZDERA Pavel
Year of publication	2001
Type	Article in Proceedings
Conference	Sborník príspevkov 53. zjazd Chemických spoločností
MU Faculty or unit	Faculty of Science
Citation
Field	Organic chemistry
Keywords	Quinazolines; thioureas; domino-reactions
Description	The intramolecular cycloaddition reaction of N1-R- or N1,N1-Di-R-N3-[[(2-cyanophenyl)imino](phenyl)-methyl]thioureas formed in situ by addition of amines to N2-(2-cyanophenyl)-N1-thioxo-methylidenebenzene-1-carboximidamide 1 were investigated. These thioureas undergo cyclization folowed by Dimroth rearrangement and quinazolin-4-yl or quinazolin-4-ylidene thioureas were identified.
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