Reversing selectivity of bambusuril macrocycles toward inorganic anions by installing spacious substituents on their portals

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Authors	RANDO Carola GREWAL Surbhi SOKOLOV Jan KULHÁNEK Petr ŠINDELÁŘ Vladimír
Year of publication	2025
Type	Article in Periodical
Magazine / Source	Chemical Science
MU Faculty or unit	Faculty of Science
Citation
web	https://pubs.rsc.org/en/content/articlelanding/2025/sc/d4sc07150f
Doi	http://dx.doi.org/10.1039/d4sc07150f
Keywords	BINDING
Attached files	2483157.pdf
Description	Two chiral bambusurils, which are diastereomers to each other, show remarkable differences in their binding affinity and selectivity toward inorganic anions as determined by isothermal titration calorimetry. These differences are explained by quantum-chemical calculations.
Related projects:	CETOCOEN Excellence Chemical modification of bambusurils for adjusting their binding affinity and selectivity RECETOX research infrastructure