Synthesis and application of additives based on trifluoroethoxy-cyclo-phosphazene into polymer nanofibers

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Authors

KOPECKÁ Radka ALBERTI Milan PŘÍHODA Jiří VORÁČ Zbyněk ZARYBNICKA Lucie

Year of publication 2020
Type Article in Periodical
Magazine / Source Tetrahedron
MU Faculty or unit

Faculty of Science

Citation
Web https://doi.org/10.1016/j.tet.2020.130999
Doi http://dx.doi.org/10.1016/j.tet.2020.130999
Keywords Hydrophobicity; Modification; Nanolayers; Polymer additives; Polyphosphazenes; Media filter
Description This paper is focused on the synthesis and application of phosphazene derivatives, hexakis(2,2,2-trifluoroethoxy)-cyclo-triphosphazene and tetrakis(2,2,2-trifluoroethoxy)-diamino-cyclo-triphosphazene. These compounds were used as additives into some common polymers. As the synthesized compounds themselves show enhanced hydrophobicity, the nanofibers, made from them by electrospinning technology, should exhibit the enhanced hydrophobicity, too. It was found that hydrophobic properties of fibers are influenced by number of trifluoroethoxy groups bound to the phosphazene cycle. The use of these modified nanofibers especially in surface protection is expected. The result of the use can be the creation of efficient, removable, compact protect layer for long-term objects storing. (C) 2020 Published by Elsevier Ltd.
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