The synthesis and comparative characterization of three novel electroactive iminoboronates containing ferrocene

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Authors	KONHEFR Martin LACINA Karel SKRUTKOVÁ LANGMAJEROVÁ Monika GLATZ Zdeněk SKLÁDAL Petr MAZAL Ctibor
Year of publication	2017
Type	Article in Periodical
Magazine / Source	Monatshefte für Chemie
MU Faculty or unit	Faculty of Science
Citation
Web	https://link.springer.com/article/10.1007/s00706-017-2028-3
Doi	http://dx.doi.org/10.1007/s00706-017-2028-3
Field	Organic chemistry
Keywords	Cyclic voltammetry;Donor-acceptor effect;Lewis acids;Metallocenes;Organometallic compounds;Schiff bases
Description	Along our way towards the advanced saccharide-sensitive probes, three novel electroactive iminoboronate regioisomers of [(ferrocenylimino)methyl]phenylboronic acid have been synthesized. The ortho, meta, and para regioisomers were characterized structurally by NMR, MS, FT-IR, UV/Vis and their electrochemical behavior in aqueous solution was studied using cyclic voltammetry. The obtained results confirmed different behavior of the ortho isomer due to an interaction of boronic acid moiety with the proximate imine group of the iminoferrocenyl residue.
Related projects:	Centrum pokročilých bioanalytických technologií Podpora biochemického výzkumu v roce 2016 CEITEC 2020 Podpora biochemického výzkumu v roce 2017