Redoxní procesy guaninových reziduí DNA heptamerů na rtuťových elektrodách
| Title in English | The Redox Processes of Guanine Residues in DNA Heptamers on Mercury Electrodes |
|---|---|
| Authors | |
| Year of publication | 2016 |
| Type | Article in Proceedings |
| Conference | XXXVI. Moderní Elektrochemické Metody |
| MU Faculty or unit | |
| Citation | |
| Field | Physical chemistry and theoretical chemistry |
| Keywords | DNA heptamers; G peak; hydrogen evolution process; pH effect; vertex potential; mercury electrode |
| Description | The paper is focused on electrochemical investigation of DNA heptamers d(GCXXXGC) with different central triplet (XXX = GAA, AAA, CCC). To evaluate the effect of hydrogen evolution on redox processes of these heptamers on a hanging mercury drop electrode, the AC reduction and G oxidation vcoltammetric peaks were measured at three pH and at different vertex potentials (from -1.60 V to -1.85 V). The double-peak G oxidation signals (GI and GII) reflect not only the structures of heptamers but also the impact of hydrogen evolution process into the production of 7,8 - dihydogenguanine moieties forming together with hydrogen in negative potentials. |
| Related projects: |