Laser ablation synthesis of new gold carbides. From gold-diamond nano-composite as a precursor to gold-doped diamonds. Time-of-flight mass spectrometric study

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Authors

HAVEL Josef PENA-MENDEZ Eladia AMATO Filippo PANYALA Nagender Reddy BURŠÍKOVÁ Vilma

Year of publication 2014
Type Article in Periodical
Magazine / Source Rapid Communications in Mass Spectrometry
MU Faculty or unit

Faculty of Science

Citation
web http://onlinelibrary.wiley.com/doi/10.1002/rcm.6783/abstract
Doi http://dx.doi.org/10.1002/rcm.6783
Field Analytic chemistry
Keywords gold carbides; laser ablation synthesis; mass spectrometry; gold-doped nano-diamonds
Description RATIONALE Gold carbides can be produced via laser ablation synthesis (LAS) from mixtures of nano-gold (NG) and various carbonaceous materials. The nano-composite of nano-gold (NG) and nano-diamond (ND) might represent a promising precursor for the generation of new gold carbides. METHODS Time-of-flight mass spectrometry (TOF MS), transmission electron microscopy (TEM) and energy-dispersive X-ray spectroscopy (EDX) were used. The stoichiometry of clusters was determined via modelling of the isotopic patterns and MSn analysis.
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