Lanthanide coordination polymers with bis(diphenylphosphoryl)bicyclo[1.1.1]pentane

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Authors	SPÍCHAL Zdeněk JANČAŘÍK Andrej MAZAL Ctibor PINKAS Jiří PEKÁRKOVÁ Pavla NEČAS Marek
Year of publication	2013
Type	Article in Periodical
Magazine / Source	Polyhedron
MU Faculty or unit	Faculty of Science
Citation
Web	http://dx.doi.org/10.1016/j.poly.2013.06.026
Doi	http://dx.doi.org/10.1016/j.poly.2013.06.026
Field	Inorganic chemistry
Keywords	Bicyclopentanes;Lanthanides;Coordination polymers;X-ray crystallography
Description	The reaction of 1,3-bis(diphenylphosphoryl)bicyclo[1.1.1]pentane (1) with lanthanide nitrates provided a series of layered network coordination polymers Ln(1)1.5(NO3)3 (Ln = Ce, Pr, Nd, Eu, Tb, Er, Yb, Lu). Crystal structures of all members of the series were determined by single crystal X-ray diffraction and were found isostructural. The compounds were studied by IR spectroscopy, luminescence spectroscopy, thermal analysis (TG/DSC) and powder X-ray diffraction (PXRD) techniques.
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