Synthesis of Organotitanium(IV) Fluoride Phosphates and the Crystal Structure of [(C5Me4Et)TiF(m-F){m-O2P(OSiMe3)2}]2

Pevec,  Andrej; Demšar,  Alojz; Pinkas,  Jiří; Nečas,  Marek

Synthesis of Organotitanium(IV) Fluoride Phosphates and the Crystal Structure of [(C5Me4Et)TiF(m-F){m-O2P(OSiMe3)2}]2

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Authors	PEVEC Andrej DEMŠAR Alojz PINKAS Jiří NEČAS Marek
Year of publication	2012
Type	Article in Periodical
Magazine / Source	Acta Chimica Slovenica
MU Faculty or unit	Central European Institute of Technology
Citation
Web	http://acta.chem-soc.si/59/59-1-203.pdf
Field	Inorganic chemistry
Keywords	titanium; fluoride; phosphate; X-ray structure
Attached files	CpTiFPO_ActaSlo-2012-59_1__203O206.pdf
Description	The complexes [(C5Me4R)TiF(m-F){m-O2P(OSiMe3)2}]2 [R = Me (1), Et (2)] were prepared from [(C5Me4R)TiF3]2, (R = Me, Et) and OP(OSiMe3)3. The molecular structure of 2 has been determined by single-crystal X-ray diffraction analysis. An eight-membered Ti2O4P2 metallacycle bridged by two fluorine ligands between two titanium centers is observed.
Related projects:	Physical and chemical properties of advanced materials and structures Reakce fosfátů a fosfonátů s fluoridy a alkoxidy titaničitými CEITEC - Central European Institute of Technology