X-ray structural characterizations of the reaction products between ZnCl2 and 6-benzylaminopurine derivatives in different acidic conditions
| Authors | |
|---|---|
| Year of publication | 2009 |
| Type | Article in Periodical |
| Magazine / Source | Journal of Molecular Structure |
| MU Faculty or unit | |
| Citation | |
| Web | http://linkinghub.elsevier.com/retrieve/pii/S0022286009003755 |
| Field | Inorganic chemistry |
| Keywords | Zinc(II) complexes; Tautomerism; Protonation; 6-Benzylaminopurine; Crystal structures |
| Description | The reaction between ZnCl2 and the corresponding 6-benzylaminopurine derivative, Ln, [where L1 = 6-(4- fluorobenzylamino)purine, L2 = 6-(2-fluorobenzylamino)purine or L3 = 6-(4-chlorobenzylamino)purine] in 0.1 M or 2 M HCl afforded various products in dependence on a pH of the reaction medium. X-ray structures of the reaction products have been determined by a single crystal X-ray analysis. Moreover, the compounds have been characterized by elemental analyses (C, H, N), FTIR and Raman spectroscopies, and thermogravimetric (TG) and differential thermal (DTA) analyses. |
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