Polymerization of Halogenophosphazenes in Capacitively Induced Plasma Discharges

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Authors

VORÁČ Zbyněk ALBERTI Milan JANČA Jan

Year of publication 2009
Type Article in Periodical
Magazine / Source Plasma Processes and Polymers
MU Faculty or unit

Faculty of Science

Citation
Field Inorganic chemistry
Keywords inorganic polymers plasma polymerization phosphazenes
Description This work deals with plasma polymerization of halogenocyclophosphazenes. Reaction products were examined by the P-31-NMR, LDI-TOF MS, DIP-MS, IR and XPS spectroscopy.Analysis demonstrated that products of plasma polymerization are similar for all halogenophosphazenes and mainly consist of branched chains. The best homogeneity, adhesion to substrate and also easiest substitution of halogen atoms by nucleophilic reagents was achieved with plasma polymerized (NPF2)3.
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