(mu(3)-Trithiocyanurato-kappa(6) N-1,S-2 : N-3, S-4 : N-5, S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa(3) N,N ',N '') zinc(II)] tris(perchlorate)

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Authors	MAREK Jaromír TRÁVNÍČEK Z. ČERMÁKOVÁ Š.
Year of publication	2007
Type	Article in Periodical
Magazine / Source	Acta Crystallographica Section E: Structure Reports Online
MU Faculty or unit	Faculty of Science
Citation
Field	Inorganic chemistry
Keywords	CRYSTAL; PERCHLORATE
Description	In the title compound, [ Zn-3( C3N3S3)(C9H23N3) 3]( ClO4) 3, the three Zn-II centres, related by the body-diagonal threefold symmetry along [ 111], are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a distorted trigonal bipyramidal geometry and bonded by three N atoms of a tridentate N, N, N', N", N"-pentamethyldiethylenetriamine ligand, and one S and one N atoms of the ttc ligand. The secondary structure is stabilized by a variety of non-bonding C-H . . O interactions, connecting the cation and perchlorate anions.
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