[mu]-Trithiocyanurato-[kappa]4N1,S2:N3,S4-bis[(N,N,N',N'',N''-pentamethyldiethylenetriamine-[kappa]3N,N',N'')zinc(II)] perchlorate monohydrate
| Authors | |
|---|---|
| Year of publication | 2007 |
| Type | Article in Periodical |
| Magazine / Source | Acta Crystallographica Section E |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | Zinc(II); trithiocyanuric acid; structure; |
| Description | In the title compound, [Zn2(C3N3S3)(C9H23N3)2]ClO4.H2O, the dinuclear ZnII metal centres are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a distorted trigonal bipyramidal geometry and bonded to three diethylenetriamine N atoms, and an S and an N atom of ttc. The crystal structure is stabilized by O-H...O, O-H...S, C-H...S and C-H...O interactions connecting the cations, the ClO4- anions and the water molecules. |
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