(N,N,N',N'',N''-Pentamethyldiethylenetriamine-[kappa]3N,N',N'')(trithiocyanurato-[kappa]2N,S)zinc(II)

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Authors	MAREK Jaromír TRÁVNÍČEK Zdeněk ČERMÁKOVÁ Šárka
Year of publication	2007
Type	Article in Periodical
Magazine / Source	Acta Crystallographica Section E: Structure Reports Online
MU Faculty or unit	Faculty of Science
Citation
Field	Inorganic chemistry
Keywords	Zinc(II); trithiocyanuric acid; structure;
Description	The structure of the title compound, [Zn(C9H23N3)(C3HN3S3)], consists of discrete molecules connected by N-H...S hydrogen bonds into centrosymmetric dimers. The ZnII atom is pentacoordinated in a deformed trigonal-bipyramidal geometry by three N atoms of a tridentate N,N,N',N'',N''-pentamethyldiethylenetriamine ligand, and one S and one N atoms of a trithiocyanurate dianion bonded as a bidentate ligand. The crystal structure is further stabilized by close contacts of the types C-H...S and C-H...N.
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