Criss-cross Cycloadditions on Ketazines Derived from Alicyclic Ketones
| Authors | |
|---|---|
| Year of publication | 2006 |
| Type | Article in Periodical |
| Magazine / Source | Molecules |
| MU Faculty or unit | |
| Citation | |
| Field | Organic chemistry |
| Keywords | Criss-cross cycloaddition; ketazines; cyclohexanone azine; cyclopentanone azine; cycloheptanone azine; substituted perhydro[1;2;4]triazolo[1;2-a][1;2;4]triazole-1;5-dione; substituted perhydro[1;2;4]triazolo[1;2-a][1;2;4]triazole-1;5-dithione; spiro compounds |
| Description | The reactivity of alicyclic ketazines in criss-cross cycloadditions was investigated. They react in the presence of acetic acid with potassium cyanate and ammonium thiocyanate to form spirocyclic perhydro[1,2,4]triazolo[1,2-a][1,2,4]triazole-1,5-diones and perhydro[1,2,4]triazolo[1,2-a][1,2,4]triazole-1,5-dithiones, respectively, in relatively high yields. |
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