Diphenyldichlorophosphonium Trichloride - Chlorine Solvate 1:1, [PPh2Cl2]+Cl3-. Cl2, an Ionic Form of Diphenyltrichlorophosphorane. Crystal Structures of [PPh2Cl2]+Cl3-. Cl2 and [(PPh2Cl2)2]2+[InCl5]2-
| Authors | |
|---|---|
| Year of publication | 2003 |
| Type | Article in Periodical |
| Magazine / Source | INORGANIC CHEMISTRY |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | ionic form of PPh2Cl3; trichloride ion; single-crystal X-ray analysis; 31P; 1H; and 35Cl-NMR; Raman spectra |
| Description | An ionic form of diphenyltrichlorophosphorane, namely, diphenyldichlorophosphonium trichloride isolated as a dichlorine solvate (1), was obtained by treating PPh2Cl3 with excess chlorine. The identity of this species was established by single-crystal X-ray analysis, 31P, 1H, and 35Cl-NMR and Raman spectra. Bis(diphenyldichlorophosphonium) pentachloroindate (2) was obtained by the reaction of diphenyltrichlorophosphorane with indium trichloride in dichloromethane for comparison purposes. Its identity was determined by 31P-NMR spectra and single-crystal X-ray analysis. |
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