Syntéza fluorodi- a fluorotrifosforečnanů.
| Title in English | Synthesis of fluorodi- and fluorotriphosphates. |
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| Authors | |
| Year of publication | 2000 |
| Type | Article in Proceedings |
| Conference | Pokroky v anorganickej chémii. Sborník prispevkov. |
| MU Faculty or unit | |
| Citation | |
| Field | Inorganic chemistry |
| Keywords | Fluorodiphosphates; Fluorotriphosphates; Synthesis;NMR spectroscopy |
| Description | The possibility of synthesis of new fluorodi- and fluorotriphosphate anions was studied by 19F and 31P NMR spectroscopy. A new 1,1,2-tri-fluorodiphosphate was obtained by the substitution of chlorine in the PO2ClF(-) anion by a -OP(O)F2 group. Similarly, the so far unknown 1,1,3,3-tetrafluorotriphosphate was synthesized by the reaction of dichlorophosphate with an excess of F2P(O)OP(O)F2. |
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